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蚂蚁淘在线 / 品牌中心 / Norgen Biotek / Norgen Biotek /Plasma/Serum Exosome and Free-Circulating RNA Isolation Mini Kit (Cat. 59500)/50preps/59500
商品描述
- Properties
- Safety
- CofA
- Technical Info
- Specifications
Purity: | 99% |
Bp: | -22.5° |
Mp: | -110° |
Pictograms: | |
Signal Word: | Warning |
Hazard Statements: | H280, H341 |
Precautionary Statements: | P201, P281, P403, P410 |
UN#: | UN1956 |
Hazard Class: | 2.2 |
RTECS: | PB6975000 |
Risk Statements: | 68 |
Safety Statements: | 36/37 |
SDS: | See MSDS |
Excepted Quantities: | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) |
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Reagent used for the trifluoromethylation of various compounds; e.g. using copper or zinc powder in the presence of various catalysts.1,2Trifluoromethyl iodide has been used for nucleophilic trifluoromethylation of aldehydes and ketones based on photoinduced reduction of trifluoromethyl iodide by tetrakis(dimethylamino)ethylene (TDAE).3The reagent is also used for the rhodium-catalyzed-trifluoromethylation of α,β-unsaturated ketones,4and enantioselectiveα-trifluoromethylation of aldehydes via photoredox organocatalysis using a readily available iridium photocatalyst and a commercial imidazolidinone catalyst.5
1.Tetrahedron Lett.2002, 43, 4317.
2.Tetrahedron Lett.1993, 34, 2169.
3.Org. Lett.2001, 3, 4271.
4.Int. J. Thermophys.2000, 21, 393.
5.J. Am. Chem. Soc.,2009, 131, 10875.
Specifications