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苏州工业园区生物纳米园A4#216
联系电话
4000-520-616 / 18915418616
传真号码
0512-67156496
电子邮箱
info@ebiomall.com
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https://www.ebiomall.com
商品描述
- Properties
- Safety
- CofA
- Technical Info
- Specifications
- BSE-TSE
| Purity: | 99% |
| Bp: | 77°/80mm |
| Density: | 1.150 |
| Refractive Index: | 1.3600 |
| Pictograms: |   |
| Signal Word: | Danger |
| Hazard Statements: | H226, H314, H318 |
| Precautionary Statements: | P201, P210, P261, P280, P301 + P330 + P331, P302 + P352, P304 + P312, P305 + P351 + P338, P310 |
| UN#: | UN2920 |
| Packing Group: | II |
| Hazard Class: | 8 , 3 |
| Flash Point: | 25° |
| SDS: | See MSDS |
| Limited Quantities: | 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid) |
| Excepted Quantities: | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
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Strong Lewis acid catalyst and highly reactive silylating agent with a much greater selectivity for C-silylation than chlorotrimethylsilane.1It is used to cleavet-butyl esters directly to trimethylsilyl esters,2promote chemoselective reactions of acyclic acetals in the presence of cyclic acetals,3promote cycloaddition of nitrones with silyl enol ethers,4catalyze the conversion of aldehydes to homoallyl ethers in an Ionic Liquid5and assist facile deprotection of N,O-Acetonides.6Employed in the synthesis of enaminones as an Activator,7one-pot synthesis of α-aminonitriles and their fluorinated analogues,8andsynthesis of N-vinyl derivatives of nucleobases as aLewis acid catalyst.9
1.J. Prakt. Chem.1999, 341, 410.
2.Org. Lett.2002, 4, 1947.
3.J. Chem. Soc., Perkin Trans. 1,1994,2357.
4.J. Chem. Soc., Perkin Trans. 1,1993,3157.
5.Synthesis,2005, 2661.
6. J. Org. Chem.2007, 73, 752.
7.Synth. Commun.1997, 27, 4275.
8.Synlett2007,2395.
9.Synthesis2002,0172.
Specifications
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