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4000-520-616 / 18915418616
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0512-67156496
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商品描述
- Properties
- Safety
- CofA
- Technical Info
- Specifications
- BSE-TSE
Purity: | 99.5% |
Bp: | 59-60° |
Mp: | -4° |
Density: | 1.596 |
Refractive Index: | 1.2750 |
Pictograms: | |
Signal Word: | Danger |
Hazard Statements: | H302, H314, H318, H361 |
Precautionary Statements: | P201, P262, P264, P280, P301 + P312, P301 + P330 + P331, P303 + P361 + P353, P304 + P340, P305 + P351 + P338, P308 + P313, P310 |
UN#: | UN3265 |
Packing Group: | II |
Hazard Class: | 8 |
RTECS: | UB6450000 |
SDS: | See MSDS |
Limited Quantities: | 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid) |
Excepted Quantities: | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
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A speciality solvent for polar polymers and organic synthesis.1,2It has also found use in biochemistry to solubilize peptides and and peptide intermediates with high solubilizing potential.3,4It’s been used inthe absenceof catalysts to allow electrophilic activation of hydrogen peroxide toward epoxidation of alkenes and the Baeyer−Villiger oxidation of ketones.5Employed as a fluorinated solvent to enhance the efficiency of rhodium(I)-catalyzed [4+2] intramolecular cycloaddition of ether-tethered alkynyl dienes and [5+2] cycloaddition of alkynyl vinylcyclopropanes.6
1.Synthesis2004, 18.
2.Synthesis2007, 2925.
3.Biochemistry1990, 29, 2639
4.Tetrahedron Lett.1995, 36, 7833.
5.Org. Lett.,2000, 2, 2861.
6.J. Org. Chem.2006, 71, 6437.
Specifications
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