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ATCC/1,1,1,3,3,3-Hexafluoro-2-propanol/003409-250g

价格
¥800.00
货号:003409-250g
浏览量:86
品牌:ATCC
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商品描述
  • Properties
  • Safety
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  • Specifications
  • BSE-TSE
Purity:99.5%
Bp:59-60°
Mp:-4°
Density:1.596
Refractive Index:1.2750
Pictograms:
Signal Word:Danger
Hazard Statements:H302, H314, H318, H361
Precautionary Statements:P201, P262, P264, P280, P301 + P312, P301 + P330 + P331, P303 + P361 + P353, P304 + P340, P305 + P351 + P338, P308 + P313, P310
UN#:UN3265
Packing Group:II
Hazard Class:8
RTECS:UB6450000
SDS: See MSDS
Limited Quantities:1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
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A speciality solvent for polar polymers and organic synthesis.1,2It has also found use in biochemistry to solubilize peptides and and peptide intermediates with high solubilizing potential.3,4It’s been used inthe absenceof catalysts to allow electrophilic activation of hydrogen peroxide toward epoxidation of alkenes and the Baeyer−Villiger oxidation of ketones.5Employed as a fluorinated solvent to enhance the efficiency of rhodium(I)-catalyzed [4+2] intramolecular cycloaddition of ether-tethered alkynyl dienes and [5+2] cycloaddition of alkynyl vinylcyclopropanes.6
1.Synthesis2004, 18.
2.Synthesis2007, 2925.
3.Biochemistry1990, 29, 2639
4.Tetrahedron Lett.1995, 36, 7833.
5.Org. Lett.,2000, 2, 2861.
6.J. Org. Chem.2006, 71, 6437.
Specifications
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