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商品描述
- Properties
- Safety
- CofA
- Technical Info
- Specifications
| Purity: | 90% |
| Mp: | 222-226°(dec.) |
| Pictograms: |  |
| Signal Word: | Warning |
| Hazard Statements: | H302, H315, H319, H335 |
| Precautionary Statements: | P261, P301 + P330 + P331, P302 + P352, P304 + P340, P305 + P351 + P338 |
| SDS: | See MSDS |
| Enter Lot No:Submit |
A reagent that can react with electrophilic carbon atoms to form methyl sulfones in a single step.1Applied in stereoselective synthesis of (E)-alkenyl sulfones from alkenes or alkynes,2preparation of branched allylic sulfones by iridium-catalyzed allylation,3reaction withα-halo ketones under microwave irradiation toafford the corresponding β-keto sulfones,4introduction of a sulfone group to pyridines and diazines,5synthesis of β-hydroxy-sulfones via opening of epoxides in ionic liquid,6preparation of aryl and alkenylsulfones from the cross-coupling reaction with organoboronic acids,7and synthesis of vinyl sulfones.8Starting material for synthesis of aryl sulfoxides and sulfonium salts in trifluoromethanesulfonic acid as a novel sulfurizing agent.9Catalyst used in preparation of heteroarenecarbonitriles,10and in synthesis of 2-aroylquinoxalines, 1-aroylphthalazines, and 4-aroylcinnolines.11
Reference
1.J. Am. Chem. Soc.1953,75, 5582.
2.Synlett2011,1308.
3.Org. Lett.2010,12,92.
4.Green Chem. Lett. Rev.2008,1,179.
5.Tetrahedron Lett.2009,50,1928.
6.J. Sulfur Chem.2007,28,513.
7.Tetrahedron2007,63,7667.
8.Synthesis2007,1465.
9.Chem. Comm.1996,2099.
10.Heterocycles1998,49,405.
11.Heterocycles1994,39,345.
