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商品描述
BoilingPoint:123°/20
MolecularWeight:244.94
AlternativeName:TRIBUTYLGERMANIUMHYDRIDE
SpecificGravity:0.916
Flashpoint:78°C(172°F)
HMISKey:3-2-1-X
Formula:C12H28Ge
Purity:99%
RefractiveIndex:1.4508
Application:Effectsfree-rADIcalreductiveadditionofalkylhalidestoolefinswithAIBN.1,2
Reducesbenzylicchlorides70Xfasterthansilylhydrides.3
Initiatesradicalcyclizationofpolyenes.4
Reference:1.Hershberger,J.TetrahedronLett.1986,26,6289.
2.Pike,P.etal.Tetrahedron1988,44,6295.
3.Mayr,H.etal.Angew.Chem.,Int.Ed.Engl.1992,31,1046.
4.Spino,C.etal.J.Org.Chem.1999,64,5292.
